How is the Rate of Appearance of NO Related to the Rate of Disappearance of O2? A Brief Guide

Nuclear reactions are processes in which the nuclei of atoms undergo changes and produce new elements or isotopes. One of the most important types of nuclear reactions is **nuclear fusion**, which is the process of combining two lighter nuclei to form a heavier one, releasing a large amount of energy in the process. Nuclear fusion is the source of energy for stars, including our Sun.

However, nuclear fusion is not easy to achieve on Earth, as it requires very high temperatures and pressures to overcome the repulsive forces between the positively charged nuclei. One of the challenges of nuclear fusion research is to find ways to control and sustain the fusion reaction for a long enough time to extract useful energy from it.

One of the possible nuclear fusion reactions that scientists are studying is the following:

$$2D + 3T \rightarrow 4He + n + 17.6 MeV$$

In this reaction, two isotopes of hydrogen, deuterium (D) and tritium (T), fuse to form an isotope of helium (He) and a neutron (n), releasing 17.6 million electron volts (MeV) of energy per reaction. Deuterium and tritium are both radioactive, but they are relatively abundant and can be extracted from water and lithium, respectively.

How to Measure the Rate of a Nuclear Fusion Reaction?

The rate of a nuclear fusion reaction is a measure of how fast the reaction is occurring, or how many fusion events are happening per unit time. The rate of a nuclear fusion reaction depends on several factors, such as:

– The temperature and pressure of the reacting nuclei

– The concentration and density of the reacting nuclei

– The cross-section or probability of the reaction

– The presence of any catalysts or inhibitors that affect the reaction

One way to measure the rate of a nuclear fusion reaction is to monitor the changes in the concentrations or amounts of the reactants and products over time. For example, in the above reaction, we can measure how fast deuterium and tritium are disappearing, or how fast helium and neutron are appearing.

However, since different reactants and products have different stoichiometric coefficients in the balanced equation, we need to account for them when comparing their rates. For example, for every two deuterium atoms that disappear, one helium atom appears. Therefore, we need to divide the rate of disappearance of deuterium by two to get the same rate as the rate of appearance of helium.

In general, we can write the following formula for relating the rates of different species in a nuclear fusion reaction:

$$\frac{d[A]}{dt} = -\frac{a}{A}\frac{d[B]}{dt} = -\frac{a}{B}\frac{d[C]}{dt} = \frac{a}{C}\frac{d[D]}{dt}$$

Where [A], [B], [C], and [D] are the concentrations or amounts of the reactants and products, respectively, a, b, c, and d are their stoichiometric coefficients in the balanced equation, respectively, and d/dt denotes the rate of change with respect to time.

How is the Rate of Appearance of NO Related to the Rate of Disappearance of O2?

To answer this question, let us consider another nuclear fusion reaction that involves nitrogen (N) and oxygen (O) as reactants and products:

$$14N + 2D \rightarrow 15O + p + 3.5 MeV$$

$$15O \rightarrow 15N + e^+ + \nu_e + 1.7 MeV$$

$$15N + D \rightarrow 12C + 4He + 4.96 MeV$$

In this reaction, nitrogen-14 (14N) and deuterium (D) fuse to form oxygen-15 (15O) and a proton (p), releasing 3.5 MeV of energy per reaction. Oxygen-15 then decays to nitrogen-15 (15N), a positron (e+), and a neutrino (\nu_e), releasing 1.7 MeV of energy per decay. Nitrogen-15 then fuses with another deuterium atom to form carbon-12 (12C) and helium-4 (4He), releasing 4.96 MeV of energy per reaction.

This reaction is also known as **the carbon-nitrogen-oxygen cycle** or **the CNO cycle**, which is one of the main sources of energy for stars heavier than our Sun.

To relate the rate of appearance of NO (nitric oxide) to the rate of disappearance of O2 (oxygen gas), we need to consider two steps:

1. The formation of NO from N and O atoms

2. The consumption of O2 by NO

The formation of NO from N and O atoms can be represented by the following equation:

$$N + O \rightarrow NO + 6.4 eV$$

Where 6.4 eV is the energy released per reaction.

The consumption of O2 by NO can be represented by the following equation:

$$2NO + O2 \rightarrow 2NO2 + 114 kJ$$

Where 114 kJ is the energy released per reaction.

Using the formula for relating the rates of different species in a nuclear fusion reaction, we can write the following equations for these two steps:

$$\frac{d[N]}{dt} = -\frac{d[O]}{dt} = -\frac{d[NO]}{dt}$$

$$\frac{d[O_2]}{dt} = -\frac{1}{2}\frac{d[NO]}{dt} = -\frac{1}{2}\frac{d[NO_2]}{dt}$$

Combining these two equations, we can get the following relation between the rate of appearance of NO and the rate of disappearance of O2:

$$\frac{d[NO]}{dt} = -\frac{1}{4}\frac{d[O_2]}{dt}$$

This means that for every four molecules of NO that appear, one molecule of O2 disappears.

Conclusion

In this article, we have explained how to measure the rate of a nuclear fusion reaction by monitoring the changes in the concentrations or amounts of the reactants and products over time. We have also shown how to relate the rates of different species in a nuclear fusion reaction by using their stoichiometric coefficients in the balanced equation. Finally, we have applied these concepts to answer the question: how is the rate of appearance of NO related to the rate of disappearance of O2? We have found that for every four molecules of NO that appear, one molecule of O2 disappears.

We hope this article has been helpful and informative for you. If you have any questions or comments, please feel free to share them with us. Thank you for reading!

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